######################DM1-Table S6###################### CLASS: GAS #gD1 CSC + OH = CSCO[O] CONST: A: 1.12E-11 E/R: 250.0 CLASS: GAS #gD2 CSC + OH = [S](C)(C)O SPEC5MCM: K1: 9.50E-39 K2: 5.27E+03 K3: 7.50E-29 K4: 5.61E+03 CLASS: GAS #gD3 [S](C)(C)O = CSC + OH SPEC8MCM: K1: 2.05E-14 K2: 2.674E+03 K3: 5.50E-31 K4: 7.46E+03 -- CLASS: GAS #gD4 [S](C)(C)O = [O]OS(C)(C)O CONST: A: 8.50E-13 -- CLASS: GAS #gD5 [S](C)(C)O = CSO + CO[O] CONST: A: 5.00E+05 -- CLASS: GAS #gD6 CSC + NO3 = CSCO[O] + HNO3 CONST: A: 1.90E-13 E/R: -520.0 -- CLASS: GAS #gD7 CSC + CL = 0.45 CSCO[O] + 0.45 HCL + 0.55 [S](C)(C)CL CONST: A: 3.40E-10 -- CLASS: GAS #gD8 CSC + BR = CSCO[O] + HBR CONST: A: 9.00E-11 E/R: 2390 -- CLASS: GAS #gD9 CSC + BR = [S](C)(C)BR CONST: K1: 3.7E-29 K2: 5.3 K3: 1.5E-10 K4: 2 -- CLASS: GAS #gD10 CSC + CLO = 0.73 CL + 0.73 CS(=O)C + 0.27 HOCL + 0.27 CSCO[O] CONST: A: 1.70E-15 E/R: -340 -- CLASS: GAS #gD11 CSC + BRO = CS(=O)C + BR CONST: A: 1.50E-14 E/R: -1000 -- CLASS: GAS #gD12 CSC + CL2 = CSCCL + HCL CONST: A: 3.40E-14 -- CLASS: GAS #gD13 CSC + IO = CS(=O)C + I CONST: A: 3.30E-13 E/R: 925 -- CLASS: GAS #gD14 CSCO[O] + HO2 = CSCOO CONST: A: 1.13E-13 E/R: -1300.0 -- CLASS: GAS #gD15 CSCO[O] + NO = CSC[O] + NO2 CONST: A: 4.90E-12 E/R: -260.0 -- CLASS: GAS #gD16 CSCO[O] + NO3 = CSC[O] + NO2 CONST: A: 2.30E-12 -- CLASS: GAS #gD17 CSCO[O] = 0.8 CSC[O] + 0.1 CSCO + 0.1 CSC=O CONST: A: 3.74E-12 -- CLASS: GAS #gD18 [O]OS(C)(C)O + NO = CS(=O)(=O)C + HO2 + NO2 CONST: A: 2.70E-12 E/R: -360.0 -- CLASS: GAS #gD19 [O]OS(C)(C)O = CS(=O)C + HO2 TEMP1: A: 8.90E+10 E/R: 6040.0 -- CLASS: GAS #gD20 CSCCL + OH = CSO + CLCO[O] CONST: A: 2.50E-12 -- CLASS: GAS #gD21 [S](C)(C)CL + NO2 = CSC + CLNO2 CONST: A: 2.70E-11 -- CLASS: GAS #gD22 [S](C)(C)CL + NO = CSC + CLNO CONST: A: 1.20E-11 -- CLASS: GAS #gD23 [S](C)(C)CL = CS(=O)C + CLO CONST: A: 4.00E-18 -- CLASS: GAS #gD24 [S](C)(C)CL = CSC + CL CONST: A: 9.00E+01 -- CLASS: GAS #gD25 [S](C)(C)BR = CS(=O)C + BRO CONST: A: 1.00E-18 -- CLASS: GAS #gD26 [S](C)(C)BR = CSC + BR CONST: A: 1.02E+04 CLASS: GAS #gD27 CSCOO + OH = CSC=O + OH CONST: A: 7.03E-11 -- CLASS: GAS #gD28 CSC[O] = C[S] + C=O CONST: A: 1.00E+06 -- CLASS: GAS #gD29 CSCO + OH = CSC=O + HO2 CONST: A: 2.78E-11 -- CLASS: GAS #gD30 CSC=O + OH = C[S] + CO CONST: A: 1.11E-11 -- CLASS: GAS #gD31 CS(=O)(=O)C + OH = [O]OCS(=O)(=O)C CONST: A: 4.40E-14 -- CLASS: GAS #gD32 CS(=O)C + OH = CS(=O)O + CO[O] TEMP1: A: 6.10E-12 E/R: -800.0 -- CLASS: GAS #gD33 CS(=O)C + NO3 = CS(=O)(=O)C + NO2 CONST: A: 2.90E-13 -- CLASS: GAS #gD34 CS(=O)C + CL = CS(=O)CO[O] + HCL CONST: A: 1.45E-11 -- CLASS: GAS #gD35 CS(=O)C + CL = C[S](=O)(CL)C CONST: A: 7.40E-11 -- CLASS: GAS #gD36 CS(=O)C + BRO = CS(=O)(=O)C + BR CONST: A: 1.00E-14 -- CLASS: GAS #gD37 C[S](=O)(CL)C = CS(=O)(=O)C + CLO CONST: A: 3.00E-18 -- CLASS: GAS #gD38 C[S](=O)(CL)C + NO = CS(=O)C + CLNO CONST: A: 1.20E-11 -- CLASS: GAS #gD39 C[S](=O)(CL)C + NO2 = CS(=O)C + CLNO2 CONST: A: 2.10E-11 -- CLASS: GAS #gD40 C[S](=O)(CL)C + C[S](=O)(CL)C = 2 CS(=O)C + CL2 CONST: A: 3.00E-11 -- CLASS: GAS #gD41 C[S](=O)(CL)C = CS(=O)C + CL CONST: A: 9.00E+01 -- CLASS: GAS #gD42 CS(=O)CO[O] + NO = CS[O] + C=O + NO2 CONST: A: 7.50E-12 -- CLASS: GAS #gD43 CS(=O)CO[O] + HO2 = CS(=O)COO CONST: A: 1.50E-12 -- CLASS: GAS #gD44 CSO + OH = CS[O] CONST: A: 5.00E-11 -- CLASS: GAS #gD45 C[S] + NO2 = CS[O] + NO CONST: A: 6.00E-11 E/R: -240.0 -- CLASS: GAS #gD46 C[S] + O3 = CS[O] CONST: A: 1.15E-12 E/R: -430.0 -- CLASS: GAS #gD47 C[S] = CSO[O] CONST: A: 1.20E-16 E/R: -1580.0 -- CLASS: GAS #gD48 [O]OCS(=O)(=O)C + HO2 = OOCS(=O)(=O)C CONST: A: 1.13E-13 E/R: -1300.0 -- CLASS: GAS #gD49 [O]OCS(=O)(=O)C + NO = [O]CS(=O)(=O)C + NO2 TEMP1: A: 2.70E-12 E/R: -360.0 -- CLASS: GAS #gD50 [O]OCS(=O)(=O)C + NO3 = [O]CS(=O)(=O)C + NO2 CONST: A: 2.30E-12 -- CLASS: GAS #gD51 [O]OCS(=O)(=O)C = 0.2 O=CS(=O)(=O)C + 0.6 [O]CS(=O)(=O)C + 0.2 OCS(=O)(=O)C CONST: A: 2.00E-12 -- CLASS: GAS #gD52 CS(=O)O + OH = CO[O] + SO2 CONST: A: 9.00E-11 -- CLASS: GAS #gD53 CS(=O)O + NO3 = C[S](=O)=O + HNO3 CONST: A: 1.00E-13 -- CLASS: GAS #gD54 CS[O] + NO2 = 0.25 CO[O] + 0.25 SO2 + 0.25 NO + 0.75 C[S](=O)=O + 0.75 NO CONST: A: 1.20E-11 -- CLASS: GAS #gD55 CS[O] + O3 = CO[O] + SO2 CONST: A: 4.00E-13 -- CLASS: GAS #gD56 CS[O] = CS(=O)O[O] CONST: A: 3.12E-16 E/R: -1580.0 -- CLASS: GAS #gD57 CSO[O] + HO2 = CSOO CONST: A: 4.00E-12 -- CLASS: GAS #gD58 CSO[O] + NO = CS[O] + NO2 CONST: A: 1.10E-11 -- CLASS: GAS #gD59 CSO[O] + NO2 = CS[O] + NO3 CONST: A: 2.20E-11 -- CLASS: GAS #gD60 CSO[O] = CO[O] + SO2 CONST: A: 5.60E+16 E/R: 10870.0 -- CLASS: GAS #gD61 CSO[O] = C[S] CONST: A: 3.50E+10 E/R: 3560.0 -- CLASS: GAS #gD62 CSO[O] = C[S](=O)=O CONST: A: 1.00E+00 -- CLASS: GAS #gD63 OOCS(=O)(=O)C + OH = O=CS(=O)(=O)C + OH CONST: A: 1.26E-12 -- CLASS: GAS #gD64 OOCS(=O)(=O)C + OH = [O]OCS(=O)(=O)C CONST: A: 3.60E-12 -- CLASS: GAS #gD65 [O]CS(=O)(=O)C = C[S](=O)=O + C=O CONST: A: 1.00E+06 -- CLASS: GAS #gD66 O=CS(=O)(=O)C + OH = C[S](=O)=O + CO CONST: A: 1.78E-12 -- CLASS: GAS #gD67 OCS(=O)(=O)C + OH = O=CS(=O)(=O)C + HO2 CONST: A: 5.23E-13 -- CLASS: GAS #gD68 OCS(=O)(=O)C + OH = [O]CS(=O)(=O)C CONST: A: 1.40E-13 -- CLASS: GAS #gD69 C[S](=O)=O + OH = CS(=O)(=O)O CONST: A: 5.00E-11 -- CLASS: GAS #gD70 C[S](=O)=O + NO2 = CS(=O)(=O)[O] + NO CONST: A: 2.20E-11 -- CLASS: GAS #gD71 C[S](=O)=O + O3 = CS(=O)(=O)[O] CONST: A: 3.00E-13 -- CLASS: GAS #gD72 C[S](=O)=O = CO[O] + SO2 CONST: A: 5.00E+13 E/R: 9673.0 -- CLASS: GAS #gD73 C[S](=O)=O = [O]OS(=O)(=O)C CONST: A: 1.03E-16 E/R: -1580.0 -- CLASS: GAS #gD74 CS(=O)O[O] + HO2 = 0.44 C[S](=O)=O + 0.44 OH + 0.41 CS(=O)OO + 0.15 CS(=O)O + 0.15 O3 CONST: A: 5.20E-13 E/R: -980.0 -- CLASS: GAS #gD75 CS(=O)O[O] + NO = C[S](=O)=O + NO2 CONST: A: 1.00E-11 -- CLASS: GAS #gD76 CS(=O)O[O] + NO2 = [O-][N+](=O)OOS(=O)C SPEC2MCM: K1: 1.20E-12 K2: -9.00E-01 K3: 0.0 -- CLASS: GAS #gD77 CS(=O)O[O] + NO3 = C[S](=O)=O + NO2 CONST: A: 4.00E-12 -- CLASS: GAS #gD78 CS(=O)O[O] = CS[O] CONST: A: 9.10E+10 E/R: 3560.0 -- CLASS: GAS #gD79 CS(=O)O[O] = 0.7 C[S](=O)=O + 0.3 CS(=O)O CONST: A: 1.00E-11 -- CLASS: GAS #gD80 CS(=O)(=O)[O] + HO2 = CS(=O)(=O)O CONST: A: 5.00E-11 -- CLASS: GAS #gD81 CS(=O)(=O)[O] = CO[O] + SULF CONST: A: 5.00E+13 E/R: 9946.0 -- CLASS: GAS #gD82 [O]OS(=O)(=O)C + HO2 = 0.41 OOS(=O)(=O)C + 0.44 CS(=O)(=O)[O] + 0.44 OH + 0.15 CS(=O)(=O)O + 0.15 O3 CONST: A: 5.20E-13 E/R: -980.0 -- CLASS: GAS #gD83 [O]OS(=O)(=O)C + NO = CS(=O)(=O)[O] + NO2 CONST: A: 1.00E-11 -- CLASS: GAS #gD84 [O]OS(=O)(=O)C + NO2 = [O-][N+](=O)OOS(=O)(=O)C SPEC2MCM: K1: 1.20E-12 K2: -9.00E-01 K3: 0.0 -- CLASS: GAS #gD85 [O]OS(=O)(=O)C + NO3 = CS(=O)(=O)[O] + NO2 CONST: A: 4.00E-12 -- CLASS: GAS #gD86 [O]OS(=O)(=O)C = C[S](=O)=O CONST: A: 3.01E+10 E/R: 3560.0 -- CLASS: GAS #gD87 [O]OS(=O)(=O)C = 0.7 CS(=O)(=O)[O] + 0.3 CS(=O)(=O)O CONST: A: 1.00E-11 -- CLASS: GAS #gD88 CS(=O)OO + OH = CS(=O)O[O] CONST: A: 9.00E-11 -- CLASS: GAS #gD89 [O-][N+](=O)OOS(=O)C + OH = CS(=O)O + NO2 CONST: A: 1.00E-11 -- CLASS: GAS #gD90 [O-][N+](=O)OOS(=O)C = CS(=O)O[O] + NO2 CONST: A: 5.40E+16 E/R: 13112.0 -- CLASS: GAS #gD91 CS(=O)(=O)O + OH = CS(=O)(=O)[O] CONST: A: 2.24E-14 -- CLASS: GAS #gD92 OOS(=O)(=O)C + OH = [O]OS(=O)(=O)C CONST: A: 3.60E-12 -- CLASS: GAS #gD93 [O-][N+](=O)OOS(=O)(=O)C + OH = [O]OS(=O)(=O)C + HNO3 CONST: A: 3.60E-13 -- CLASS: GAS #gD94 [O-][N+](=O)OOS(=O)(=O)C = [O]OS(=O)(=O)C + NO2 CONST: A: 5.40E+163 E/R: 13112.0 ########??????????????in pdf E+163????????????????? -- #########################DM1-Table S7###################### CLASS: GAS #gPD1 CSCOO = CSC[O] + OH PHOTMCM: I: 7.649E-06 M: 6.820E-01 N: 2.790E-01 -- CLASS: GAS #gPD2 CSC=O = C[S] + CO + HO2 PHOTMCM: I: 2.792E-05 M: 8.050E-01 N: 3.380E-01 -- CLASS: GAS #gPD3 OOCS(=O)(=O)C = [O]CS(=O)(=O)C + OH PHOTMCM: I: 7.649E-06 M: 6.820E-01 N: 2.790E-01 -- CLASS: GAS #gPD4 O=CS(=O)(=O)C = C[S](=O)=O + CO + HO2 PHOTMCM: I: 2.792E-05 M: 8.050E-01 N: 3.380E-01 -- CLASS: GAS #gPD5 CS(=O)OO = C[S](=O)=O + OH PHOTMCM: I: 7.649E-06 M: 6.820E-01 N: 2.790E-01 -- CLASS: GAS #gPD06 OOS(=O)(=O)C = CS(=O)(=O)[O] + OH PHOTMCM: I: 7.649E-06 M: 6.820E-01 N: 2.790E-01 -- CLASS: GAS #gPD07 CS(=O)COO = CS[O] + C=O + OH PHOTMCM: I: 7.649E-06 M: 6.820E-01 N: 2.790E-01 -- CLASS: GAS #gPD08 CSCCL = C[S] + CLCO[O] PHOTMCM: I: 1.458E-04 M: 3.140E-01 N: 6.410E-01 -- CLASS: GAS #gPD09 CSOO = CS[O] + OH PHOTMCM: I: 7.649E-06 M: 6.820E-01 N: 2.790E-01 ############################DM1-Table S9###################### CLASS: AQUA #aD1 aCSC + aO3 = aCS(=O)C + aO2 CONST: A: 8.61E+08 B: -2600.0 -- CLASS: AQUA #aD2 aCSC + aHO = aCS(=O)C + aHO2 - aO2 CONST: A: 1.90E+10 B: 0.0 -- CLASS: AQUA #aD3 aCSC + CL2m = a[S](C)(C)CL + CLm CONST: A: 3.00E+09 B: 0.0 -- CLASS: AQUA #aD4 aCSC + BR2m = a[S](C)(C)BR + BRm CONST: A: 3.20E+09 B: 0.0 -- CLASS: AQUA #aD5 aCSC + aH2O2 = aCS(=O)C + [aH2O] CONST: A: 3.40E-02 B: 0.0 -- CLASS: AQUA #aD6 a[S](C)(C)CL + aO2 = aCS(=O)C + aCLO CONST: A: 2.41E3 B: 0.0 -- CLASS: AQUA #aD7 a[S](C)(C)BR + aO2 = aCS(=O)C + aBRO CONST: A: 6.02E2 B: 0.0 -- CLASS: AQUA #aD8 aCS(=O)C + aO3 = aCS(=O)(=O)C + aO2 CONST: A: 7.00E+00 B: 0.0 -- CLASS: AQUA #aD9 aCS(=O)C + aHO = aCS(=O)O + a[C] CONST: A: 6.65E+09 B: -1270.0 -- CLASS: AQUA #aD10 aCS(=O)C + SO4m = aC[S+](=O)C + SO4mm CONST: A: 2.97E+09 B: -1440.0 -- CLASS: AQUA #aD11 aCS(=O)C + aCL = aC[S](=O)(CL)C CONST: A: 6.30E+09 B: 0.0 -- CLASS: AQUA #aD12 aCS(=O)C + CL2m = aC[S](=O)(CL)C + CLm CONST: A: 1.60E+07 B: 0.0 -- CLASS: AQUA #aD13 aCS(=O)C + aH2O2 = aCS(=O)(=O)C + [aH2O] CONST: A: 2.75E-06 B: 0.0 -- CLASS: AQUA #aD14 aC[S+](=O)C + BRm = aC[S](=O)(BR)C CONST: A: 5.00E9 B: 0.0 -- CLASS: AQUA #aD15 aC[S](=O)(BR)C + BRm = aCS(=O)C + BR2m CONST: A: 2.60E8 B: 0.0 -- CLASS: AQUA #aD16 aC[S](=O)(CL)C + [aH2O] = aCS(=O)O + aHCL + a[C] CONST: A: 1.00E+07 B: 0.0 -- CLASS: AQUA #aD17 aC[S](=O)(O)C = aCS(=O)O + a[C] CONST: A: 1.00E+07 B: 0.0 -- CLASS: AQUA #aD18 aCS(=O)(=O)C + aHO = aCS(=O)(=O)[C] + [aH2O] CONST: A: 1.77E+07 B: -1690 -- CLASS: AQUA #aD19 aCS(=O)(=O)C + SO4m = aCS(=O)(=O)[C] + SO4mm + Hp CONST: A: 3.95E+06 B: -1360 -- CLASS: AQUA #aD20 aCS(=O)(=O)C + aCL = aCS(=O)(=O)[C] + aHCL CONST: A: 8.20E+05 B: 0.0 -- CLASS: AQUA #aD21 aCS(=O)(=O)C + CL2m = aCS(=O)(=O)[C] + aHCL + CLm CONST: A: 8.24E+03 B: 0.0 -- CLASS: AQUA #aD22 aCS(=O)(=O)[C] + aO2 = aCS(=O)(=O)CO[O] CONST: A: 2.00E+09 B: 0.0 -- CLASS: AQUA #aD23 aCS(=O)(=O)CO[O] = aC[S](=O)=O + aC=O + aO2 CONST: A: 7.00E+03 B: 0.0 -- CLASS: AQUA #aD24 aCS(=O)O + aO3 = aCS(=O)(=O)O + aO2 CONST: A: 3.50E+07 B: 0.0 -- CLASS: AQUA #aD25 aCS(=O)O + aHO = aC[S](=O)(O)O CONST: A: 6.00E+09 B: 0.0 -- CLASS: AQUA #aD26 aCS(=O)[O-] + aHO = 0.9 aC[S](=O)=O + 0.9 OHm + 0.1 a[C] + 0.1 HSO3m CONST: A: 1.20E+10 B: 0.0 -- CLASS: AQUA #aD27 aCS(=O)[O-] + SO4m = aC[S](=O)=O + SO4mm CONST: A: 1.00E+09 B: 0.0 -- CLASS: AQUA #aD28 aCS(=O)[O-] + CL2m = aC[S](=O)=O + 2 CLm CONST: A: 8.00E+08 B: 0.0 -- CLASS: AQUA #aD29 aCS(=O)[O-] + aH2O2 = aCS(=O)(=O)[O-] + [aH2O] CONST: A: 1.20E-02 B: 0.0 -- CLASS: AQUA #aD30 aCS(=O)[O-] + aO3 = aCS(=O)(=O)[O-] + aO2 CONST: A: 2.00E+06 B: 0.0 -- CLASS: AQUA #aD31 aC[S](=O)(O)O + aO2 = aCS(=O)(=O)O + aHO2 CONST: A: 1.20E+09 B: 0.0 -- CLASS: AQUA #aD32 aCS(=O)(=O)O + aHO = a[C]S(=O)(=O)O + [aH2O] CONST: A: 1.50E+07 B: 0.0 -- CLASS: AQUA #aD33 aCS(=O)(=O)[O-] + aHO = a[C]S(=O)(=O)[O-] + [aH2O] CONST: A: 1.29E+07 B: -2630 -- CLASS: AQUA #aD34 aCS(=O)(=O)[O-] + SO4m = aCS(=O)(=O)[O] + SO4mm CONST: A: 1.13E+04 B: -2490 -- CLASS: AQUA #aD35 aCS(=O)(=O)[O-] + aCL = aCS(=O)(=O)[O] + CLm CONST: A: 4.90E+05 B: 0.0 -- CLASS: AQUA #aD36 aCS(=O)(=O)[O-] + CL2m = aCS(=O)(=O)[O] + 2 CLm CONST: A: 3.89E+03 B: 0.0 -- CLASS: AQUA #aD37 aC[S](=O)=O + aHO = aCS(=O)(=O)O CONST: A: 1.00E+10 B: 0.0 -- CLASS: AQUA #aD38 aC[S](=O)=O + aO3 = aCS(=O)(=O)[O] + aO2 CONST: A: 1.50E+09 B: 0.0 -- CLASS: AQUA #aD39 aC[S](=O)=O + SO3mm = aCS(=O)[O-] + SO4mm + Hp – [aH2O] CONST: A: 1.70E+09 B: 0.0 -- CLASS: AQUA #aD40 aC[S](=O)=O = a[C] + aSO2 CONST: A: 8.30E+04 B: 0.0 -- CLASS: AQUA #aD41 aC[S](=O)=O + aO2 = aCS(=O)(=O)O[O] CONST: A: 1.20E+09 B: 0.0 -- CLASS: AQUA #aD42 aC[S](=O)=O + aC[S](=O)=O = aCS(=O)O + aCS(=O)(=O)O – [aH2O] CONST: A: 9.00E+08 B: 0.0 -- CLASS: AQUA #aD43 aCS(=O)(=O)O[O] + aCS(=O)[O-] = aCS(=O)(=O)[O-] + aCS(=O)(=O)[O] CONST: A: 6.20E+08 B: 0.0 -- CLASS: AQUA #aD44 aCS(=O)(=O)[O] + aCS(=O)[O-] = aCS(=O)(=O)[O-] + aC[S](=O)=O CONST: A: 1.00E+08 B: 0.0 -- CLASS: AQUA #aD45 aCS(=O)(=O)[O] = a[C] + aSO3 CONST: A: 8.30E+04 B: 0.0 -- CLASS: AQUA #aD46 aCS(=O)(=O)[O] + aHO2 = aCS(=O)(=O)O + aO2 CONST: A: 8.3E+05 B: 0.0 -- CLASS: AQUA #aD47 a[C]S(=O)(=O)O + aO2 = a[O]OCS(=O)(=O)O CONST: A: 2.00E+09 B: 0.0 -- CLASS: AQUA #aD48 a[C]S(=O)(=O)[O-] + aO2 = a[O]OCS(=O)(=O)[O-] CONST: A: 2.00E+09 B: 0.0 -- CLASS: AQUA #aD49 a[O]OCS(=O)(=O)[O-] + Hp = aC=O + Hp + SO3m + 0.5 aO2 CONST: A: 7.00E+03 B: 0.0 ########################DM1 Table S10######################################## CLASS: DISS #1 aCS(=O)O = aCS(=O)[O-] + Hp CONST: A: 5.0E-03 B: 5.00E+10 CLASS: DISS #2 aCS(=O)(=O)O = aCS(=O)(=O)[O-] + Hp CONST: A: 73 B: 5.00E+10 CLASS: DISS #3 a[O]OCS(=O)(=O)O = a[O]OCS(=O)(=O)[O-] + Hp CONST: A: 73 B: 5.00E+10 CLASS: DISS #4 CLm + aC[S+](=O)C = aC[S](=O)(CL)C CONST: A: 330 B: 3.03E+07 CLASS: DISS #5 aC[S+](=O)C + [aH2O] = aC[S](=O)(O)C + Hp DCONST: A: 2.5E-06 B: 5.00E+10